Friday, October 2, 2009

Synthetics, simulants, and enhancements > Synthetics

Six crystals of cubo-octahedral shapes, each about 2 millimeters in diameter. Two are pale blue, one is pale yellow, one is gree-blue, one is dark blue and one green-yellow.
Synthetic diamonds of various colors grown by the high-pressure high-temperature technique

Synthetic diamonds are diamond crystals that are manufactured in a laboratory, as opposed to natural diamonds which form naturally within the Earth. The gemological and industrial uses of diamond have created a large demand for rough stones. This demand has been satisfied in large part by synthetic diamonds, which have been manufactured by various processes for more than half a century. However, in recent years it has become possible to produce gem-quality synthetic diamonds of significant size.[33]

The majority of commercially available synthetic diamonds are yellow in color and produced by so called High Pressure High Temperature (HPHT) processes.[83] The yellow color is caused by nitrogen impurities. Other colors may also be reproduced such as blue, green or pink, which are a result of the addition of boron or from irradiation after synthesis.[84]

A round, clear gemstone with many facets, the main face being hexagonal, surrounded by many smaller facets.
Colorless gem cut from diamond grown by chemical vapor deposition

Another popular method of growing synthetic diamond is chemical vapor deposition (CVD). The growth occurs under low pressure (below atmospheric pressure). It involves feeding a mixture of gases (typically 1 to 99 methane to hydrogen) into a chamber and splitting them to chemically active radicals in a plasma ignited by microwaves, hot filament, arc discharge, welding torch or laser.[85] This method is mostly used for coatings, but can also produce single crystals several millimeters in size (see picture).[39]

At present, the annual production of gem quality synthetic diamonds is only a few thousand carats, whereas the total production of natural diamonds is around 120 million carats. Despite this fact, a purchaser is more likely to encounter a synthetic when looking for a fancy-colored diamond because nearly all synthetic diamonds are fancy-colored, while only 0.01% of natural diamonds are fancy-colored.[86]

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